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Synthesis and luminescence properties of rare earth ternary complexes consisting of Eu(III), β-diketones and 1,10-phenanthroline 被引量：1

Synthesis and luminescence properties of rare earth ternary complexes consisting of Eu(III), β-diketones and 1,10-phenanthroline
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摘要 Three novel β-diketones （HPPP, HTPP, and HFPP） ligands were synthesized by Sonogashira coupling reaction and Claisen condensation. The structure of β-diketones was confirmed with elemental analysis, IR, NMR and MS spectra. Three new ternary complexes consisting of Eu（Ⅲ）, β-diketones, and 1,10-phenanthroline（phen） were synthesized and characterized as TbL3phen （L=PPP, TPP, FPP） with elemental analysis, chemical analysis, and IR spectra, and their luminescence properties were studied. Three novel β-diketones （HPPP, HTPP, and HFPP） ligands were synthesized by Sonogashira coupling reaction and Claisen condensation. The structure of β-diketones was confirmed with elemental analysis, IR, NMR and MS spectra. Three new ternary complexes consisting of Eu（Ⅲ）, β-diketones, and 1,10-phenanthroline（phen） were synthesized and characterized as TbL3phen （L=PPP, TPP, FPP） with elemental analysis, chemical analysis, and IR spectra, and their luminescence properties were studied.
作者 刘兴旺 王娜 索全伶
机构地区 School of Chemical Engineering Baotou Teacher’s College
出处 《Journal of Rare Earths》 SCIE EI CAS CSCD 2008年第6期778-782,共5页 稀土学报（英文版）
基金 supported by the Natural Science Foundation of Inner Mongolia (200508010210) the Education Department of Inner Mongolia (NJ06002, NJcxy08124) Science and Technology Bureau of Baotou (2007G1013)
关键词 Β-DIKETONE ternary complex luminescence property rare earths β-diketone ternary complex luminescence property rare earths
分类号 TG146.45 [金属学及工艺—金属材料]
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参考文献10

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Journal of Rare Earths
2008年 第6期

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