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∧-related Quantum Interference of ^2П [Case(a)] Diatom on Rotational Energy Transfer 被引量:2

∧-related Quantum Interference of ^2П [Case(a)] Diatom on Rotational Energy Transfer
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摘要 理论上在 collisional 量干扰学习在不可分的干扰角度和散布角度之间的关系,原子的不可分的干扰角度 --<SUP>2</SUP>&#8719;[case(a)] 两价的分子系统被描述。理论上模仿实验,在一个原子的导致碰撞的旋转精力转移上的理论模型 --<SUP>2</SUP>&#8719;[case(a)] 硅藻系统基于第一份订单被介绍远程的相互作用潜力考虑的出生的近似。为 <SUP>2</SUP>&#8719;在 Hund 的盒子(a) 硅藻的电子状态,干扰的度被讨论。导致碰撞的旋转精力的干扰角度 CN 转(在 Hund 的盒子(a) 与的 <SUP>2</SUP>&#8719;) 他, Ne,和 Ar 被计算份量上。在不可分的干扰角度的决心的关键参数被获得。 To study theoretically the relationship between the integral interference angle and the scat- tering angle in collisional quantum interference, the integral interference angle of atom- ^2П[case(a)] diatomic molecules system is described. To simulate the experiment theoretically, the theoretical model on collision-induced rotational energy transfer in an atom- ^2П[case(a)]diatom system is presented based on the first order Born approximation taking into account of the long-range interaction potential. For the ^2П electronic state in the Hund's case(a) diatom, the degree of the interference is discussed. The interference angles of collision-induced rotational energy transfer of CN(A^2П) in Hund's case(a) with He, Ne, and Ar are calculated quantitatively. The key parameters in the determination of integral interference angles are obtained.
出处 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2009年第1期13-18,共6页 化学物理学报(英文)
基金 ACKNOWLEDGMENTS This work was supported by the National Natural Science Foundation of China (No.10374040) and the Fund of the Educational Department of Liaoning Province of China (No.20060347 and No.2008290).
关键词 干涉角 散射 双原子分子系统 硅藻系统 Collisional quantum interference, Rotational energy transfer, Interference angle
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