摘要
综述了近年来对合成金属富勒烯包合物衍生物的研究进展。Diels-Alder、1,3-偶极、硅烷化、羟基化、Bingel-Hirsch等是合成金属富勒烯包合物衍生物的主要方法,而碳笼内包合的簇的种类不同程度上影响着化学反应过程和金属富勒烯包合物衍生物的性能,这些金属富勒烯包合物衍生物所具有的新性能,在医药、材料和电子器件具有广阔的应用前景,同时展望了今后的工作。
The recent research progress in the synthesis of endohedral metallofullerene derivatives during last decade is summarized in this review. Diels-Alder reaction, 1,3-dipoles reaction, silylation reaction, Bingel-Hirsch reaction, hydroxylation reaction etc are the main methods for the preparation of endohedral metallofullerene derivatives. The different types of clusters inserted in carbon cage are important in determining the chemical reaction process of endohedral metallofullerenes and the properties of endohedral metallofullerene derivatives in varying degrees. These derivatives have new properties and have a much better application future in the domain of medicine, material and electronic apparatus. The research work in future is predicted.
出处
《材料导报》
EI
CAS
CSCD
北大核心
2009年第5期63-67,共5页
Materials Reports
基金
国家自然科学基金资助项目(No.10576026)
国家863项目(No.2007AA03Z329)
关键词
金属富勒烯包合物
合成
性能
endohedral metallofullerenes, synthesis, properties
