摘要
研究了氟化膦类系列配位体（ＧＰＦ２：Ｇ＝Ｆ，Ｅｔ２Ｎ，Ｍｅ２Ｎ，Ｃ５Ｈ１０Ｎ，ｎＰｒＯ，ＰｈＯ，ｎｅｏＰｎＯ，２，５ｄｉＭｅＰｈ，ｉｓｏＰｒ，ｅｔｃ．）及其与金属镍（０）铜（Ｉ）钼（０）金（Ｉ）形成的配合物的核磁共振氟谱化学位移的定量分子建模，发现了其中的一些有用规律．
Systematic investigation was made on Nuclear Magnetic Resonance (NMR). In this article, a series of various ligands of phosphorus fluoride (GPF 2) where G=F(PF 3), Et 2N, Me 2N, C 5H 10 N, nPrO, PhO, neoPnO, 2,5 diMePh, isoPr, etc., and their complexes with several metallic ions and/or atoms such as Ni(0), Cu(I), Mo(0) and Au(I) were examined deeply. Molecular modelling was quantitatively done for\ 19 F NMR chemical shifts. Some useful rules were found.
出处
《波谱学杂志》
CAS
CSCD
北大核心
1998年第1期65-71,共7页
Chinese Journal of Magnetic Resonance
基金
国家教委与自然科学基金
机械部跨世纪人才专项基金
日本文部省与科学振兴会资助
关键词
氟谱
氟化膦配体
金属配合物
化学位移
NMR
Chemical shifts of\ 19 F, Various ligands of phosphorus fluoride, Complexes with metallic ions and atoms, Ni(0),Mo(0),Cu(I) and Au(I), Quantitative molecular modelling
