NO分子(5σ)~2(1π)~43p-(5σ)~2(1π)~3(2π)~2构形相互作用与转动能级结构

(5σ)2(1π)43p(5σ)2(1π)3(2π)2CONFIGURATION INTERACTION AND ROTATIONAL ENERGY STRUCTURE OF THE NO MOLECULE

在考虑ＮＯ分子的（５σ）２（１π）４３ｐ－（５σ）２（１π）３（２π）２构形相互作用的情况下，对Ｄ２Σ＋（ｖ＝６），Ｃ２Π（ｖ＝６），Ｂ２Π（ｖ＝２４）和Ｌ２Π（ｖ＝４）电子态的转动能级结构以及态函数进行了计算，计算结果与实验结果很相符。

ased on the consideration of (5σ)2(1π)43p(5σ)2(1π)3(2π)2configuration interaction, the rotational eneries and wavefunctions for the excited states D2Σ+(vD=6),C2Π(vC=6), B2Π(vB=24) and L2Π(vL=4) of the NO molecule have been calculated, the results are in good agreement with the experimental data.