V-E传能中原子荧光辐射束缚的理论处理

THEORETICAL TREATMENT OF RADIATION TRAPPING OFATOMIC FLUORESCENCE IN V E ENERGY TRANSFER

Ｖ－Ｅ传能中原子荧光辐射束缚的理论处理＠王储记＠王坚＠马兴孝￥中国科学技术大学化学物理系ＶＥ传能中原子荧光辐射束缚的理论处理王储记王坚马兴孝（中国科学技术大学化学物理系，合肥２３００２６）（１９９６年７月１２日收到；１９９７年１０月２７日收到修改稿）...

Abstract A differential integral equation system of Holstein type is used to describe the kinetic process in V E energy transfer between molecules and atoms with radiation trapping.A reduced solution of a finite series has been presented,which allows to describe the whole temporal behavior of fluorescence.The further derivative is an analytical expression of the fluorescence decay rate as a function of rate constants and the maximum eigenvalue of the integral operator appearing in the rate equations.This will be especially useful and convenient for experimental determinations.Results are schematically illustrated and mutually compared by means of numerical calculations.