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烷氧基稀土钠簇合物SmNa_8(O^tBu)_(10)(OH)的合成及催化性能初探

Synthesis of lanthanide-sodium alkoxide cluster SmNa_8(O^tBu)_(10)(OH) and its catalytic activity
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摘要 用定量加入NaOH的方法高产率地合成了烷氧基稀土钠簇合物SmNa8(OtBu)10(OH),并对其进行了X射线晶体结构鉴定.此外,将其对芳醛的Tishchenko反应的催化活性进行了初探. The lanthanide-sodium alkoxide cluster SmNa8 （O^t Bu）10 （OH） was synthesized in high yields by adding a certain amount of NaOH, and its structure was confirmed by X-ray. Moreover, its catalytic activity was tested for the Tishchenko reaction of aromatic aldehydes.
作者 厉兰 吁诚铭 徐凡 沈琪
机构地区 苏州大学化学化工学院
出处 《苏州大学学报（自然科学版）》 CAS 2009年第1期72-76,共5页 Journal of Soochow University(Natural Science Edition)
基金 国家自然科学基金资助项目(20572077 20632040)
关键词 烷氧基 簇合物 催化 Tishchenko alkoxide cluster catalysis, Tishchenko.
分类号 O643.4 [理学—物理化学]
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参考文献13

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苏州大学学报（自然科学版）
2009年 第1期

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