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丙烯酸酯-苯乙烯-马来酸酐三元共聚物降凝剂的制备 被引量:16

Preparation of acrylate-styrene-maleic anhydride terpolymer as pour point depressant
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摘要 采用溶液聚合法合成丙烯酸酯—苯乙烯—马来酸酐三元共聚物作为柴油降凝剂.以正交试验设计法对工艺条件进行优化,试验结果表明:n(丙烯酸酯):n(苯乙烯):n(马来酸酐)=9:1:1、引发剂质量分数0.8%、反应温度90℃、反应时间8 h为最佳条件,降凝剂收率为64.15%,降凝剂质量分数为0.1%时,研究的3种柴油组分油的凝点分别降低了10,5,7℃,具有良好的降凝效果. An acrylat-tyrene-maleic anhydride terpolymer as pour point depressant for diesel fuel was synthesized through solution polymerization. The optimized reaction conditions were the proper ratio of monomers 9 : 1 : 1, quantity of initiator 0.8% (based on the mass of monomers), reaction time 8 h, reaction temperature 90 ℃. The results showed that the yield was 64.15%, the pour points of three kinds of the diesel fuel might depress 10, 5 and 7 ℃ respectively, when the addition of the terpolymer was 0.1% (based on the mass of diesel fuel).
出处 《兰州大学学报(自然科学版)》 CAS CSCD 北大核心 2009年第1期69-72,共4页 Journal of Lanzhou University(Natural Sciences)
关键词 降凝剂 溶液聚合 正交试验 丙烯酸酯—苯乙烯-马来酸酐 柴油 pour point depressant solution polymerization orthogonal design acrylate-styrene-maleic anhydride diesel fuel
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