摘要
The intrinsic kinetic models of the Langmuir-Hinshelwood type were investigated in terms of the reaction rates of CO hydrogenation and CO_2 hydrogenation in theform of reactant fugacity. The parameters were estimated by the Universal Global Optimization using the Marquardt method. Residual error distribution and statistic tests show thatthe intrinsic kinetic models are reliable and acceptable. The mathematic model of a combined converter formed by gas-cooled and water-cooled reactor was developed and thegas-cooled reactor and the water-cooled reactor were characterized with one-dimensionalmathematic model. The distributions of temperature and concentration in the catalytic bedof the gas-cooled reactor and the water-cooled reactor in a combined converter with ayield of 1.2 Mt/a were simulated. The parallel cross linking pore model was used to describe the transfer process of multi-component diffusion system in the catalyst. The calculated value computed by the internal diffusion efficiency factor calculation model established for methanol synthesis catalyst fit the experimental value very well.
The intrinsic kinetic models of the Langmuir-Hinshelwood type were investigated in terms of the reaction rates of CO hydrogenation and CO2 hydrogenation in the form of reactant fugacity. The parameters were estimated by the Universal Global Optimization using the Marquardt method. Residual error distribution and statistic tests show that the intrinsic kinetic models are reliable and acceptable. The mathematic model of a combined converter formed by gas-cooled and water-cooled reactor was developed and the gas-cooled reactor and the water-cooled reactor were characterized with one-dimensional mathematic model. The distributions of temperature and concentration in the catalytic bed of the gas-cooled reactor and the water-cooled reactor in a combined converter with a yield of 1.2 Mt/a were simulated. The parallel cross linking pore model was used to describe the transfer process of multi-component diffusion system in the catalyst. The calculated value computed by the internal diffusion efficiency factor calculation model established for methanol synthesis catalyst fit the experimental value very well.
基金
Supported by the National Science & Technology Support Project Task of China(2006BAE02B02)
