摘要
用邻苯二腈和FeCl3、ZnCl2.6H2O为原料,以离子液体[bmim]BF4为溶剂合成铁酞菁PcFe和锌酞菁PcZn;用红外及紫外光谱对其进行表征;相比液相法合成酞菁,可避免溶剂有毒、易挥发等缺点,离子液体可重复利用且活性不降低。
PcFe and PcZn were synthesized respectively using FeCl3 ,ZnCl2·6H2O and phthalonitrile in [ bmim] BF_4, and characterized by IR and UV. It avoids the disadvantages of the poisonous solvents to a certain extent. The ionic liquid can be used repeatedly, and its activity doesn＇ t reduce. So it accords with the requirements of green chemistry.
出处
《济南大学学报（自然科学版）》
CAS
北大核心
2009年第2期159-161,共3页
Journal of University of Jinan(Science and Technology)
基金
山东省教育厅科技计划(J06D01)
济南大学博士基金(B0537)
