摘要
Fabrication of Gd2O2S：Pr scintillation ceramics by 2Gd2O3.（Gd,Pr）2（SO4）3.mH2O precursor was made Gd2O3, Pr6O11 and H2SO4 as the starting materials pressureless reaction sintering was investigated. The by hydrothermal reaction using commercially available Then single phase Gd2O2SO4：Pr powder was obtained by calcining the precursor at 750℃ for 2 h. The Gd2O2SO4：Pr powder compacts can be sintered to single phase Gd2O2S：Pr ceramics with a relative density of 99% and mean grain size of 30um at 1750℃ for 2 h in flowing hydrogen atmosphere. Densification and microstructural development of the Gd2O2S：Pr ceramics were examined. Luminescence spectra of the Gd2O2S：Pr ceramic under 309 nm UV excitation and X-ray excitation show a green emission at 511 nm as the most prominent peak, which corresponds to the ^3p0-3H4 transition of Pr^3＋ ions.
Fabrication of Gd2O2S：Pr scintillation ceramics by 2Gd2O3.（Gd,Pr）2（SO4）3.mH2O precursor was made Gd2O3, Pr6O11 and H2SO4 as the starting materials pressureless reaction sintering was investigated. The by hydrothermal reaction using commercially available Then single phase Gd2O2SO4：Pr powder was obtained by calcining the precursor at 750℃ for 2 h. The Gd2O2SO4：Pr powder compacts can be sintered to single phase Gd2O2S：Pr ceramics with a relative density of 99% and mean grain size of 30um at 1750℃ for 2 h in flowing hydrogen atmosphere. Densification and microstructural development of the Gd2O2S：Pr ceramics were examined. Luminescence spectra of the Gd2O2S：Pr ceramic under 309 nm UV excitation and X-ray excitation show a green emission at 511 nm as the most prominent peak, which corresponds to the ^3p0-3H4 transition of Pr^3＋ ions.
基金
supported by the National Natural Sci-ence Foundation of China (Grant. No. 50672014)
the National Science Fund for Distinguished Young Scholars,China (Grant No. 50425413)
