钴卟啉三嗪类化合物的合成与表征

Synthesis and characterization of triazine-based 5-(4-hydrox-yphenyl)-10,15,20-triphenyl cobaltporphyrin

以单羟基苯基钴卟啉与三聚氯氰为原料,通过亲核取代反应合成了钴卟啉的三嗪类化合物,以硅胶为固定相,二氯甲烷为洗脱剂采用柱层析的方法对产物进行分离和提纯。最后采用紫外可见光谱、红外光谱等手段对合成产物进行了结构表征,对主要的紫外光谱、红外光谱吸收带进行了经验归属,初步确定了合成产物的结构。

Triazine-based 5-（4-hydroxyphenyl）-10,15,20-triphenyl cobaltporphyrin was prepared by the nucleophilic substitution of hydroxy porphyrin monomers to cyanuric chloride. They were purified on silica gel using dichloromethane as washing agent. The main spectra of UV, IR spectrum showed that the structure of the target products.