期刊文献+

TiO_2/SiO_2纳米介孔复合薄膜的制备及其光催化降解性能研究 被引量:3

Preparation of Porous TiO_2/SiO_2 Nanocomposite Films and Their Photoc Atalytic Properties in Ammonia Degradation
下载PDF
导出
摘要 采用两步溶胶-凝胶法制备了TiO2/SiO2纳米介孔复合薄膜,经X-射线衍射(XRD)、傅立叶变换红外光谱(FTIR)和透射及扫描电子显微镜(TEM,SEM)表征,显示介孔复合薄膜中锐钛矿型TiO2纳米粒子均匀分散在SiO2介孔基底中,经光催化降解氨气的试验,结果表明该介孔复合薄膜的光催化活性比普通的TiO2粒子有较大的提高。 Nanosized composite films of TiO2/SiO2 were fabricated by a two-step solgel method. A series of characterizations of X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectra and transmission electron microscopy (TEM) revealed that anatase nanoparticles dispersed homogeneously in the matrix of porous silica film. Thus prepared nanocomposite films exhibited higher efficiency than the conventional counterparts in the photoc atalytic degradation of gaseous ammonia under the same conditions.
出处 《安全与环境工程》 CAS 2009年第2期40-43,47,共5页 Safety and Environmental Engineering
基金 国家科技部科技支撑计划专题项目(2006BAK01B03-1)资助
关键词 TiO2/SiO2介孔复合薄膜 氨气 光催化降解 porous composite film of TiO2/SiO2 ammonia photoc atalysis degradation
  • 相关文献

参考文献9

  • 1高濂,郑珊,张青红.纳米氧化钛光催化材料及其应用[M].北京:化学工业出版社,2003.
  • 2朱新锋,杨家宽,肖波.强化二氧化钛光催化氧化技术的研究进展[J].化工环保,2004,24(6):421-425. 被引量:12
  • 3董永春,白志鹏,张利文,王宗爽,朱坦.纳米TiO_2负载织物对室内空气中氨的净化[J].中国环境科学,2005,25(B06):26-29. 被引量:10
  • 4Kistler, S. S. Coherent expanded aerogels[J]. J. Phys. Chem. , 1932,36(1) ,52-64.
  • 5Liu,Z. ,R. J. Davis. Investigation of the structure of microporous Ti-Si mixed oxides by X-ray, UV reflectance, FT-Raman, and FT-IR spectroscopies[J]. J. Phys. Chem,. 1994,98(4):1 253-1 261.
  • 6Rao, A. , V. N. N. Parvathy. Effect of gel parameters on monolithieity and density of silica aerogels[J]. J. Mater. Sci. , 1993,28 (11):3 021-3 026.
  • 7Tang,J. W. , H. D. Quan,J. H. Ye. Photoc atalytic properties and photoinduced hydrophilicity of surface-fluorinated TiO2 [J]. Chem. Mater. ,2007,19(1) :116-122.
  • 8Tanaka,K. ,M. F. V. Capule,T. Hisanaga. Effect of crystallinity of TiO2 on its phot'C atalytic action[J]. Chem. Phys. Lett., 1991,187(1-2):73-76.
  • 9Lisebigler, A. L. , G. Lu, J. T. Yates. Photoe atalysis on TiO2 surface : principle, mechanisms, and selected results [J], Chem. Rev. ,1995,95(3):735-738.

二级参考文献37

  • 1[1]Fujishima A, Honda K. Electrochemical photolysic of pater at semiconductor electrode. Nature, 1972,37 ( 1 ): 2381~ 245
  • 2[2]Carey J H,Lawrence J,Tosine H M. Photodechiorination of PCB in the presence of titanium dioxide in aqueous auspensions. Bull of Environ Contam Toxic, 1976,16 ( 6 ): 697 ~701
  • 3[4]Ronaldo Pelegrini, Patricio Peralta - Zamora, Adalgisa R, et al. Electrochemically assisted photocatalytic degradation reactive dyes. Applied Catalysis B: Environmental, 1999,22:83~99
  • 4[5]ChihCheng Sun, TseChuan Chou. Electrochemically promoted photocatalytic oxidation of nitrite ion by using rutile form of TiO2/Ti electrode. Journal of Molecular Catalysis A: Chemical, 2000,151:133 ~ 145
  • 5[6]Anthony Byrne J, Brian Eggins R. Photoelectrochemistry of oxalate on particulate TiO2 electrodes. Jourmal of Electroanalytical Chemistry, 1998,457: 61
  • 6[8]TaiCheng,XiHai Zhu, Ya Xiong. Feasibility study of photoelectrochemical degradation of methylene blue with three dimensional electrode - photocatalytic reactor. Chemosphere, 2002,46: 897 ~ 903
  • 7[9]Patrik Kopf, Ernst Gilbert, Siegfried H Eberle. TiO2 photocatalytic oxidation of monochloroacetic acid and pyridine:influence of ozone. Journal of Photochenistry and Photobiology A: Chemistry, 2000,136:163 ~ 168
  • 8[10]Isil Akmehmet Balcioglu, Nicola Getoff, Miray Bekbolet. A Comparative study for the synergistic effect of ozone on the r- irradiated and photocatalytic reaction of 4 - chlorobenzaldehyde. Journal of Photochemistry and Photobiology A:Chemistry, 2000,135: 229~ 233
  • 9[17]Juan Matos,Jorge Laine,Jean - Marie Herrmann. Synergy effect in the phorocatalytic degradation of phenol on a suspended minture of titania and activated carbon. Applied Catalysis B:, 1998,18:281 ~291
  • 10[18]Jean - Marie Herrmann, Juan Matos, Jean Disdier, et al.Solar photocatalytic degradation of 4 - Chlorophenol using the synergistic effect between titania and activated carbon in aqueous suspension. Catalysis Today, 1999, 54:255 ~265

共引文献21

同被引文献55

引证文献3

二级引证文献20

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部