摘要
以聚四氟乙烯(PTFE)纤维为基质,以甲基丙烯酸缩水甘油酯(GMA)为单体,通过辐照接枝聚合制备了PTFE-g-GMA纤维,用聚乙烯亚胺(PEI)与PTFE-g-GMA纤维进行开环反应制得新型吸附剂PTFE-g-GMA-PEI.考察了PTFE-g-GMA-PEI吸附剂对溶液中胆红素的吸附动力学、吸附量及pH、离子强度及温度等因素对胆红素吸附的影响.实验结果表明,该吸附剂对胆红素有较高的吸附容量及良好的选择吸附性能,其吸附行为遵循Langmu ir吸附模式.
The adsorbent of bilirubin based on radiation-induced graft polymerization with GMA polytetrafluoroethylene (PTFE) fiber was prepared by ^60Co and by subsequent chemical modification of the epoxy group of PTFE-g-GMA fiber with PEI. The highest amino content on the PTFE-g-GMA-PEI fiber is 1.87 mmol/g. The effect of pH, ionic strength, temperature, BSA, initial bilirubin concentration and adsorption dynamics on the adsorption capacity of PTFE-g-GMA-PEI fiber for bilirubin were investigated in a batch system. Experi- mental data indicate that the adsorption capacity of the urn, and in near neutral solution of pH = 6.5, the grafted fiber is greatly affected by the pH of the medi- grafted fiber have the highest adsorption capacity(9.6 mg/ g). The bilirubin adsorption on the PTFE-g-GMA-PEI fiber obeyed the Langmuir model. Besides, the PTFE- g-GMA-PEI fiber has the considerablely competitive ability to combine bilirubin with BSA.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
2009年第3期618-624,共7页
Chemical Journal of Chinese Universities
基金
天津市应用基础及前沿技术研究计划(批准号:08JCYBJC11300)资助
关键词
聚四氟乙烯纤维
辐照接枝
胆红素吸附
Polytetrafluoroethylene (PTFE) fiber
Irradiation grafting
Bilirubin adsorption