几个吸附等温模型热力学参数的计算方法

Method of Calculating the Thermodynamic Parametres from Some Isothermal Absorption Models

从等温吸附与解吸动力学方程出发，针对理想气体与实际气体吸附过程中活化能的不同变化规律，推导出具有与标准平衡常数ＫθＰ等价的不同吸附／解吸平衡常数Ｋ，并给出了其热力学参数的计算方法。

The calculation of the thermodynamic parametres from Langmuir Model parametre K have been reported vastly.However,when the absorption isothermal models do not accord with the Langmuir Model but accord with the Henry Model,Temkin Model or Freundlich Model,the thermodynamic parameters of the process can be adopted.This article gives the method of how to get the thermodynamic parameters from these models.