3-甲基-4-对甲苯基-5-(2-吡啶基)-1,2,4-三唑-铜(Ⅱ)配合物(英文)

Copper(Ⅱ) Complex Based on 3-Methyl-4-(4-methylphenyl)-5-(2-pyridyl)-1,2,4-triazole

A copper(Ⅱ) complex [CuL(H2O)(Sal)]·0.5H2O was obtained by the reaction of copper(Ⅱ) salicylate with 3-methyl-4-(4-methylphenyl)-5-(2-pyridyl)-1,2,4-triazole(L) in ethanol-water solution at room temperature.The crystal belongs to triclinic system with space group P1,and a=0.913 6(4) nm,b=1.122 2(5) nm,c=1.263 3(7) nm,α= 67.10(2)°,β=76.31(3)°,γ=68.17(2)°,V= 1.101(1) nm3,Z=2.The final refinement gave R1=0.039 8 and wR2=0.106 0 for 3 453 reflections with I>2σ(I).This complex is a good purple fluorescent material in solid state at room temperature.

A copper（Ⅱ） complex [CuL（H2O）（Sal）]·0.5H2O was obtained by the reaction of copper（Ⅱ） salicylate with 3- methyl-4-（4-methylphenyl）-5-（2-pyridyl）-1,2,4-triazole （L） in ethanol-water solution at room temperature. The crystal belongs to triclinic system with space group P^-1, and a=0.913 6（4） nm, b=1.122 2（5） nm, c=1.263 3（7） nm, α= 67.10（2）°,β=76.31（3）°, γ=68.17（2）°, V= 1.101（1） nm^3, Z=2. The final refinement gave R1=0.039 8 and wR2=0.106 0 for 3 453 reflections with I〉2σ（I）. This complex is a good purple fluorescent material in solid state at room temperature. CCDC： 685713.