氨基苯甲酸三苯基锡酯的酰化和缩合反应及产物的热分析研究

Acylation and Condensation of Triphenyltin 4-Aminobenzoate and Thermoanalysis of Their Products

4-氨基苯甲酸三苯基锡酯与酸酐和醛进行酰化和缩合反应,合成了10个N-三苯基锡基胺羰基苯甲酸和亚胺类化合物。热分析表明亚胺10分子中Sn-Ph键比Sn-Bu键稳定。

Ten organotin compounds have been synthesized by acylation and condensation of triphenyltin 4 - aminobenzoate with organic anhydrides and aromatic aldehydes. The thermoanalysis of binuclear organotin imine(10) demonstrates that the Sn - Ph bond'is more stable than the Sn - Bu one.