摘要
银离子交换分子筛上一氧化氮的吸附性能张文祥贾明君于剑锋吴通好（吉林大学化学系，长春１３００２３）八寻秀典岩本正和（北海道大学触媒研究中心，日本札幌０６０）关键词银，离子交换，分子筛，一氧化氮，吸附态分类号Ｏ６４７／Ｘ５氮氧化合物（ＮＯｘ）是酸雨和空...
The adsorption performance of NO on Ag-exchanged zeolites was examined by adsorptiondesorption measurement in a fixed-bed flow apparatus. The amounts of reversible (Qre) and irreversible (Qir) NO adsorption were changed with the zeolite structure. Among the samples tested, Ag-mordenite and AgZSM_5 showed the greatest ability for reversible NO adsorption. The amounts Q* of reversible and irreversible NO adsorption per Ag atom increased with decreasing Al content in the zeolites. The Q*re was constant, independent of the Ag exchange degree for ZSM_5, but increased with the exchange degree for mordenite. It was also found that the adsorption performance was dependent on adsorption temperature and pressure: Qre and Qir of Ag-mordenite increased with decreasing adsorption temperature and with increasing adsorption pressure.
出处
《催化学报》
SCIE
EI
CAS
CSCD
北大核心
1998年第2期184-186,共3页
基金
国家自然科学基金
