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水性丙烯酸-聚氨酯微乳液的制备及粒子形态 被引量:31

The Particle Size and Morphology Studies of Waterborne Acrylic-Polyurethane Hybrid Microemulsions
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摘要 Core/shell type acrylic-polyurethane hybrid microemulsions in which polyurethaneas the shell and acrylic polymer as the core were prepared successfully. Different cross-link-ing structures between core and shell can be formed by introducing hydroethyl acrylate andadipoyl dihydrazine at the ends of the polyurethane chains. The photon correlation spec-troscopy studies revealed that the mean particle size of the emulsions were smaller than 200nm. The particle morphology results revealed the core/shell structure of the uncross-linkingtype microemulsions and interpenetrating networks of the cross-linking type microemulsions. Core/shell type acrylic-polyurethane hybrid microemulsions in which polyurethaneas the shell and acrylic polymer as the core were prepared successfully. Different cross-link-ing structures between core and shell can be formed by introducing hydroethyl acrylate andadipoyl dihydrazine at the ends of the polyurethane chains. The photon correlation spec-troscopy studies revealed that the mean particle size of the emulsions were smaller than 200nm. The particle morphology results revealed the core/shell structure of the uncross-linkingtype microemulsions and interpenetrating networks of the cross-linking type microemulsions.
出处 《应用化学》 CAS CSCD 北大核心 1998年第1期101-103,共3页 Chinese Journal of Applied Chemistry
关键词 聚氨酯 微乳液粒 制备 核壳结构 水性 丙烯酸 polyurethane, microemulsion particle,preparation,core/shell structure
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参考文献1

  • 1Yi H J,Proceedings of the 22th Waterborne High Solids and Powder Coatings Symposium,1995年

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