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液体混合物的过量焓热力学模型 被引量:4

THERMODYNAMIC MODEL OF EXCESS ENTHALPY FOR LIQUID MIXTURES
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摘要 A thermodynamic model of excess enthalpy with three parameters for binary liquid mixtures is established by introducing the internal pressure and energy of vaporization of components.The calculated results of excess enthalpy for sixty─seven systems indicate that it can be applicable to various binary liquid mixtures satisfactorily. A thermodynamic model of excess enthalpy with three parameters for binary liquid mixtures is established by introducing the internal pressure and energy of vaporization of components.The calculated results of excess enthalpy for sixty─seven systems indicate that it can be applicable to various binary liquid mixtures satisfactorily.
出处 《化工学报》 EI CAS CSCD 北大核心 1998年第1期103-110,共8页 CIESC Journal
基金 国家自然科学基金!29676011
关键词 内压 蒸发能 过量焓 热力学模型 溶液 internal pressure,energy of vaporization,excess enthalpy,thermodynamic model
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参考文献1

  • 1Chen S A,Chem Eng Sci,1978年,33卷,153页

同被引文献15

  • 1彭钦华,李总成,李以圭.应用正规溶液理论计算含水体系液液平衡[J].高校化学工程学报,1994,8(2):97-105. 被引量:3
  • 2WANG F A,WANG W C,JIANG Y L,et al.A new model of dielectric constant for binary solutions [ J]. Chem Eng Technol, 2000,23: 623 - 627.
  • 3WANG F A,CHEN H S,ZHU J Q,et al. Estimation of excess enthalpy for binary systems[J]. Chem Eng J, 2002,85:235 - 243.
  • 4PRIETO G, NOGUEIRA P, BRAVO R, et al. Excess enthalpies and excess volumes of (pentan - 2 - one + an n -alkan- 1 ol) at the temperature 298.15 K[J].J Chem Thermodynamics, 1992, 24:905 - 912.
  • 5WANG F A, JIANG Y L, WANG W C.Group theoretical model of surface tension for binary solutions [ J]. Chem Eng Technol, 1997,20: 313 - 316.
  • 6Hu Y,Fluid Phase Equilibria,1993年,83卷,289页
  • 7Hu Y,Macromolecules,1991年,24卷,4356页
  • 8Wang F A, Chen H S, Zhu J Q, Song J C, Wang Z C. Estimation of excess enthalpy for binary systems. Chemical Engineering Journal, 2002,85:235-243.
  • 9Ortega J, Espiau F, Toledo F J. Thermodynamic properties of (an ester + an alkane).ⅩⅥ. experimental H E m and V E m values and a new correlation method for (an alkyl ethanate + an n-alkane) at 318.15K. J. Chem. Thermodynamics, 2004,36:193-209.
  • 10Rogalski M, Malanowski S. A new equation for correlation of vapour-liquid equilibrium of strongly non-ideal mixtures.Fluid Phase Equilibria, 1977,1: 137-152.

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