摘要
异羟肟酸类氧载体新模型化合物研究阳华秦圣英＊吕志凤周先礼李建章卢晓霞（四川大学化学系，成都６１００６４）关键词异羟肟酸钴（Ⅱ）配合物氧载体氧合反应催化环氧化中图分类号Ｏ６１３．６１仿生氧载体研究，已成为当今生物有机和生物无机化学家最关注的课题之一。在...
Equilibrium constants and thermodynamic constants ΔH 0、ΔS 0 for oxygenation of coblat(Ⅱ) complexes of nine hydroxamic acids were first determined in pyridine as solvent at different temperatures.The effects of the ligand structure on dioxygen affinities of these complexes were discussed and styrene epoxidation catalyzed by some complexes was prelimirily investigated.
出处
《化学研究与应用》
CAS
CSCD
1998年第1期86-88,共3页
Chemical Research and Application
关键词
异羟肟酸
氧载体
氧合反应
仿生氧载体
钴配合物
Hydroxamic acid,Cobalt(Ⅱ) complex,Oxygen carrier,Oxygenation,Catalytic epoxidation
