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O/W微乳中的2,4-二硝基氯苯水解反应 被引量:3

Hydrolysis of 2,4-Dinitrochlorobenzene in O/W Microemulsions
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摘要 The catalysis of O/W microemulsions of cetyltrimethylammonium bromide(CTAB),butyl alcohol, benzene and water to the hydrolysis of 2,4-dinitrochlorobenzene(DNCB) was stud-ied. Hydrolysis of DNCB in microemulsions under mormal normal temperature and normal pressure wasrealized. The results showed that the rate constants of hydrolysis of DNCB decreased with theincrease of benzene content and the ratio of cosurfactant to CTAB. As cosurfactant, t-butylalcoholis better than n-butyl alcohol for the reaction. The catalysis of O/W microemulsions of cetyltrimethylammonium bromide(CTAB),butyl alcohol, benzene and water to the hydrolysis of 2,4-dinitrochlorobenzene(DNCB) was stud-ied. Hydrolysis of DNCB in microemulsions under mormal normal temperature and normal pressure wasrealized. The results showed that the rate constants of hydrolysis of DNCB decreased with theincrease of benzene content and the ratio of cosurfactant to CTAB. As cosurfactant, t-butylalcoholis better than n-butyl alcohol for the reaction.
出处 《物理化学学报》 SCIE CAS CSCD 北大核心 1998年第3期257-260,共4页 Acta Physico-Chimica Sinica
基金 国家自然科学基金!29733110
关键词 微乳液 二硝基氯苯 水解 CTAB Microemulsion , 2,4-Dinitrochlorobenzene, Cetyltrimethylammonium bromide
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参考文献2

  • 1沈吉静,高等学校化学学报,1997年,18卷,1167页
  • 2李干佐,微乳液的原理及应用,1995年,47页

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