期刊文献+

温敏性微凝胶的研究技术 被引量:4

Techniques in the Study of Temperature-sensitive Microgels
下载PDF
导出
摘要 温敏性微凝胶因具有尺寸小、对温度的变化响应速度快、渗透性好等优点,所以在许多领域显示出良好的应用前景。温敏性微凝胶的应用性能取决于由其结构所决定的物理化学性能。为了深入了解温敏性微凝胶的结构与性能关系,研究人员利用不同技术手段进行了广泛研究。本文主要综述了显微技术、示差扫描量热技术、光散射技术、中子散射技术、核磁共振及荧光光谱等在温敏性微凝胶结构与性能研究中的应用、主要研究结果,并对微凝胶未来的研究方向提出了一些建议。 Temperature-sensitive microgels show potential application prospects in many areas, contributing to their advantages such as small sizes, the rapid response to changes in temperature and the good permeability. The application performance of temperature-sensitive microgels depends on their physicochemical properties, which are dependent on their structures. In order to elucidate the relations between the structure and properties of temperature- sensitive microgels,a wide variety of research has been carried out through various techniques. In this paper,the main techniques utilized in the study of temperature-sensitive microgels, including microscopy technique, differential scanning calorimetry, light scattering, neutron scattering, nuclear magnetic resonance and fluorescence spectroscopy, are reviewed as well as the primary results obtained. The future directions in the study of temperature-sensitive microgels are suggested finally.
作者 马晓梅 宁强
出处 《高分子通报》 CAS CSCD 北大核心 2009年第4期25-30,共6页 Polymer Bulletin
关键词 微凝胶 核磁共振 原子力显微镜 中子散射 光散射 Microgels Nuclear magnetic resonance Atomic force microscopy Neutron scattering Light scattering
  • 相关文献

参考文献59

  • 1Pelthon R H, Chibante P. Colloid Surface, 1986,20 (3) : 247 - 256.
  • 2Makino K, Hiyoshi J, Ohshima H. Colloid Surface B, 2001,20(4) : 341 - 346.
  • 3Holtz J H, Asher S A. Nature, 1997,389(6653) : 829 - 832.
  • 4Bergbreiter D E, Case B L, Liu Y S, et al. Macromolecules, 1998,31 (18) : 6053 - 6062.
  • 5Debord J D, Eustis S, Debord S B, et al. Adv Mater,2002,14(9):658- 662.
  • 6Liu H Y,Zhu X X. Polymer, 1999,40(25):6985 - 6990.
  • 7Jones C D,Lyon L A. Macromolecules,2000,33(22) :8301 - 8306.
  • 8Kratz K, Lapp A, Eimer W, Hellweg T. Colloids Surf A, 2002,197 ( 1 ) : 55 - 67.
  • 9Kratz K, Hellweg T, Eimer W. Colloid Surface A, 2000,170 (2 - 3 ) : 137 - 149
  • 10Zhou G, Elaissari A, Delair T, et al. Colloid Polym Sci, 1998,276(12) :1131 - 1139.

二级参考文献19

  • 1马晓梅,朱路,席靖宇,赵喜安,唐小真.含功能性羟基的温敏性聚(N-异丙基丙烯酰胺)微凝胶的制备及性能研究[J].高分子学报,2005,15(2):197-202. 被引量:6
  • 2马晓梅,唐小真.侧链含不同功能性羟基的温敏性N-异丙基丙烯酰胺共聚物微凝胶的制备及性能比较[J].高分子学报,2006,16(8):937-943. 被引量:9
  • 3Pelton R H, Chibante P. Preparation of Aqueous Lattices with N-isopropylacrylamide [J]. Colloid and Surf, 1986, 20(3) : 247 - 256.
  • 4Snowden M J, Chowdhary B Z. Small Sponges with Big Appetites [J]. Chem Brit, 1995, 31: 943 -945.
  • 5Debord J D, Lyon L A. Synthesis and Characterization of pH-Responsive Copolymer Microgels with Tunable Volume Phase Transition Temperatures [J]. Langmuir, 2003, 19(18): 7662-7664.
  • 6Ma X M, Xi J Y, Huang X B, et al. Novel Hydrophobically Modified Temperature-Sensitive Microgels with Tunable Volume-Phase Transition Temperature [J].Mater Lett, 2004, 58(27 - 28) : 3400 - 3404.
  • 7Kratz K, Hellweg T, Eimer W. Influence of Charge Density on the swelling Poly (N-isopropylacrylamide-co-acrylic acid) Microgels [J].Colloid Surf A, 2000, 170(2 - 3) : 137 - 149.
  • 8Hoffman A S. Hydrogels for Biomedical Applications [J]. Adv Drug Deliv Rev, 2002, 54:3 - 12.
  • 9Debord J D, Eustis S, Debord S B, et al. Color-Tunable Colloidal Crystals from Soft Hydrogel Nanoparticles [J].Adv Mater, 2002, 14(9): 658-662.
  • 10Holtz J H, Holtz J S W, Munro C H, et al. Intelligent Polymerized Crystalline Colloidal Arrays: Novel Chemical Sensor Materials[J]. Anal Chem, J998, 70(4): 780-791.

同被引文献83

引证文献4

二级引证文献5

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部