期刊文献+

Electrical Property of La_(0.7)Sr_(0.3)Cr_(0.5-y)Mn_(0.5-z)Co_((y+z))O_(3±δ) as Anode of SOFC

Electrical Property of La_(0.7)Sr_(0.3)Cr_(0.5-y)Mn_(0.5-z)Co_((y+z))O_(3±δ) as Anode of SOFC
下载PDF
导出
摘要 La0.7Sr0.3Cr0.5Mn0.4Co0.1O3±δ anode material was synthesized by glycine nitrate process. X-ray diffraction patterns indicate that single perovskite phase was created after sintering the predecessor at 1623 K for 5 h. By means of four-probe direct current, the electrical conductivities of La0.7Sr0.3Cr0.5Mn0.4Co0.1O3±δ were tested in different atmospheres, the maximum values were 10.2 S·cm-1 in air, 4.5 S·cm-1 in CH4 and 0.42 S·cm-1 in H2 at 1073 K, respectively. The compatibility between La0.7Sr0.3Cr0.5Mn0.4Co0.1O3±δ and La0.9Sr0.1Ga0.8Mg0.2O3-δ were investigated via X-ray diffraction and scanning electron microscopy, which shows that La0.7Sr0.3Cr0.5Mn0.4Co0.1O3±δ oxide, has good chemical and thermal compatibility with La0.9Sr0.1Ga0.8Mg0.2O3-δ. An electrolyte supported single cell consisted of La0.7Sr0.3Cr0.5Mn0.4Co0.1O3±δ|La0.9Sr0.1Ga0.8Mg0.2O3-δ|La0.9Sr0.1Ca0.1Fe0.8Co0.2O3±δ was fabricated through screen printing method. The open circuit voltage of the cell is about 0.92 V, and the maximum power density is about 75 mW·cm-2 at 1123 K. La0.7Sr0.3Cr0.5Mn0.4Co0.1O3±δ anode material was synthesized by glycine nitrate process. X-ray diffraction patterns indicate that single perovskite phase was created after sintering the predecessor at 1623 K for 5 h. By means of four-probe direct current, the electrical conductivities of La0.7Sr0.3Cr0.5Mn0.4Co0.1O3±δ were tested in different atmospheres, the maximum values were 10.2 S·cm-1 in air, 4.5 S·cm-1 in CH4 and 0.42 S·cm-1 in H2 at 1073 K, respectively. The compatibility between La0.7Sr0.3Cr0.5Mn0.4Co0.1O3±δ and La0.9Sr0.1Ga0.8Mg0.2O3-δ were investigated via X-ray diffraction and scanning electron microscopy, which shows that La0.7Sr0.3Cr0.5Mn0.4Co0.1O3±δ oxide, has good chemical and thermal compatibility with La0.9Sr0.1Ga0.8Mg0.2O3-δ. An electrolyte supported single cell consisted of La0.7Sr0.3Cr0.5Mn0.4Co0.1O3±δ|La0.9Sr0.1Ga0.8Mg0.2O3-δ|La0.9Sr0.1Ca0.1Fe0.8Co0.2O3±δ was fabricated through screen printing method. The open circuit voltage of the cell is about 0.92 V, and the maximum power density is about 75 mW·cm-2 at 1123 K.
出处 《Journal of Rare Earths》 SCIE EI CAS CSCD 2007年第S1期382-386,共5页 稀土学报(英文版)
基金 the National Natural Science Foundation of China (50204007) Program for New Century ExcellentTalents in University (NCET-07-0387) the Talent Foundation of Yunnan Province (2005PY01-33)
关键词 PEROVSKITE glycine nitrate process ANODE solid oxide fuel cell rare earths perovskite glycine nitrate process anode solid oxide fuel cell rare earths
  • 相关文献

参考文献3

二级参考文献12

共引文献10

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部