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Effects of Cu addition on growth of Au-Sn intermetallic compounds at Sn-xCu/Au interface during aging process

Effects of Cu addition on growth of Au-Sn intermetallic compounds at Sn-xCu/Au interface during aging process
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摘要 The growth of Au-Sn intermetallic compounds(IMCs) is a major concern to the reliability of solder joints in microelectronic,optoelectronic and micro-electronic-mechanical system(MEMS) which has a layer of Au metallization on the surface of components or leads.This paper presented the growth behavior of Au-Sn IMCs at interfaces of Au metallization and Sn-based solder joints with the addition of Cu alloying element during aging process,and growth coefficients of the Au-Sn IMCs were calculated.Results on the interfacial reaction between Sn-xCu solders and Au metallization during aging process show that three layers of Au-Sn IMCs including AuSn,AuSn2 and AuSn4 formed at the interface region.The thickness of each Au-Sn IMC layer vs square root of aging time follows linear relationship.Calculation of the IMC growth coefficients shows that the diffusion coefficients decrease with the addition Cu elements,which indicates that Cu addition suppresses the growth of Au-Sn IMCs layer. The growth of Au-Sn intermetallic compounds(IMCs) is a major concern to the reliability of solder joints in microelectronic,optoelectronic and micro-electronic-mechanical system(MEMS) which has a layer of Au metallization on the surface of components or leads.This paper presented the growth behavior of Au-Sn IMCs at interfaces of Au metallization and Sn-based solder joints with the addition of Cu alloying element during aging process,and growth coefficients of the Au-Sn IMCs were calculated.Results on the interfacial reaction between Sn-xCu solders and Au metallization during aging process show that three layers of Au-Sn IMCs including AuSn,AuSn2 and AuSn4 formed at the interface region.The thickness of each Au-Sn IMC layer vs square root of aging time follows linear relationship.Calculation of the IMC growth coefficients shows that the diffusion coefficients decrease with the addition Cu elements,which indicates that Cu addition suppresses the growth of Au-Sn IMCs layer.
出处 《Rare Metals》 SCIE EI CAS CSCD 2007年第S1期331-337,共7页 稀有金属(英文版)
基金 This work was financially supported by the National Natural Science Foundation of China ( No 50675047/ E052105) Joint Project between Samsung Electronics Co Ltd( Korea) and Harbin Institute of Technology( HIT)
关键词 Sn-based solder alloys Cu alloying element Au-Sn intermetallic compounds Sn-based solder alloys Cu alloying element Au-Sn intermetallic compounds
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参考文献11

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