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Effects of Gd^(3+) on Luminescence Properties of Eu^(3+) within Polymeric Structure in Aqueous Solutions

Effects of Gd^(3+) on Luminescence Properties of Eu^(3+) within Polymeric Structure in Aqueous Solutions
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摘要 ?6′ tetracarboxy 4,4′ bipyridine was synthesized and the luminescence enhancement of their Eu 3+ complexes by Gd 3+ was observed. The results indicate that the mechanism of enhancement is based on the formation of a polymeric structure where Eu 3+ and Gd 3+ are linked together by the ligands, which favours the consequent transfer of absorbed energy along the polymeric chain through several ligands toward the Eu 3+ . ?6′ tetracarboxy 4,4′ bipyridine was synthesized and the luminescence enhancement of their Eu 3+ complexes by Gd 3+ was observed. The results indicate that the mechanism of enhancement is based on the formation of a polymeric structure where Eu 3+ and Gd 3+ are linked together by the ligands, which favours the consequent transfer of absorbed energy along the polymeric chain through several ligands toward the Eu 3+ .
出处 《Journal of Rare Earths》 SCIE EI CAS CSCD 2001年第1期11-14,共4页 稀土学报(英文版)
基金 ProjectsupportedbytheNationalNaturalScienceFoundationofChina (2 970 10 0 6-HHS)andNaturalScienceFoundationofGuangdongProvince
关键词 rare earths europium complex intramolecular energy transfer co luminescence rare earths europium complex intramolecular energy transfer co luminescence
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  • 1戚文彬,表面活性剂与分析化学.上,1986年

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