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Effect of Barium-Precursors on Reaction Kinetics in Y-Ba-Cu-O System

Effect of Barium-Precursors on Reaction Kinetics in Y-Ba-Cu-O System
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摘要 The reactions of stoichiometric Y2O3, CuO, and different Ba salts or oxides (BaCO3, Ba(NO3)(2), BaO2, BaCuO2) for forming various compounds in the Y-Ba-Cu-O system (i.e., YBa2Cu3O7-delta, BaCuO2, Y2BaCuO5 and Y2Cu2O5) were systematically investigated by thermal analysis and X-ray diffractometry. The relevant activation energies were calculated from thermogravimetric data. It is found that the reaction pathway significantly depends on the thermal stability of the Ba precursors. Binary BaO-CuO phases form at low temperature (650 similar to 700 degreesC) when in presence of easy- to -decompose Ba precursors, and then slowly transform to ternary compounds. On the contrary, when Ba ions are released at temperature higher than 900 degreesC, ternary phases form directly from the components. The reactions of stoichiometric Y2O3, CuO, and different Ba salts or oxides (BaCO3, Ba(NO3)(2), BaO2, BaCuO2) for forming various compounds in the Y-Ba-Cu-O system (i.e., YBa2Cu3O7-delta, BaCuO2, Y2BaCuO5 and Y2Cu2O5) were systematically investigated by thermal analysis and X-ray diffractometry. The relevant activation energies were calculated from thermogravimetric data. It is found that the reaction pathway significantly depends on the thermal stability of the Ba precursors. Binary BaO-CuO phases form at low temperature (650 similar to 700 degreesC) when in presence of easy- to -decompose Ba precursors, and then slowly transform to ternary compounds. On the contrary, when Ba ions are released at temperature higher than 900 degreesC, ternary phases form directly from the components.
作者 王龙妹
出处 《Journal of Rare Earths》 SCIE EI CAS CSCD 2001年第4期241-245,共5页 稀土学报(英文版)
基金 ProjectsupportedbytheNationalNaturalScienceFoundationofItaly
关键词 rare earths Y-BA-CU-O precursors SEQUENCING KINETICS rare earths Y-Ba-Cu-O precursors sequencing kinetics
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参考文献9

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