Unexpected Stereospecific Rearrangement-Addition Reaction of Trisubstituted Gibberellin Epoxides with Trimethylaluminium

Unexpected Stereospecific Rearrangement-Addition Reaction of Trisubstituted Gibberellin Epoxides with Trimethylaluminium

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摘要 A novel rearrangement-addition reaction of trisubstituted gibberellin epoxides with trimethylaluminium is reported. The reaction proceeds stereospecifically to give tertiary methyl alcohols. The possible mechanism for the reaction is also discussed.

作者 An Qi CHEN Christine L.WILLIS

机构地区 Department of Chemistry School of Chemistry

出处《Chinese Chemical Letters》 SCIE CAS CSCD 2001年第10期855-858,共4页 中国化学快报（英文版）

基金 This work is supported by the Ministry of Education under Scientific Research Foundation for Returned Overseas Chinese Scholars.

关键词 GIBBERELLIN EPOXIDE TRIMETHYLALUMINIUM rearrangement-addition reaction gibberellin epoxide trimethylaluminium rearrangement-addition reaction

分类号 O629 [理学—有机化学]

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Chinese Chemical Letters

2001年第10期

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Unexpected Stereospecific Rearrangement-Addition Reaction of Trisubstituted Gibberellin Epoxides with Trimethylaluminium

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