Asymmetric Addition of Diethylzinc to Aldehydes Catalyzed by Chiral γ_Amino Alcohols 被引量：1

Asymmetric Addition of Diethylzinc to Aldehydes Catalyzed by Chiral γ_Amino Alcohols

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摘要 New chiral gamino alcohols 1-4 were synthesized and applied in the asymmetric addition of diethylzinc to aldehydes to give sec-alcohol with up to 94.0% enantiomeric excess. New chiral gamino alcohols 1-4 were synthesized and applied in the asymmetric addition of diethylzinc to aldehydes to give sec-alcohol with up to 94.0% enantiomeric excess.

作者 Qian Yong XU Tong Xing WU Xin Fu PAN

机构地区 Department of Chemistry

出处《Chinese Chemical Letters》 SCIE CAS CSCD 2001年第12期1055-1056,共2页 中国化学快报(英文版)

基金 Hong Kong Polytechnic University for the financial support.

关键词 Asymmetric addition gamino alcohols diethylzinc. Asymmetric addition gamino alcohols diethylzinc.

分类号 O643.3 [理学—物理化学]

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1Olusegun B. Olubanwo,James A. Golen,Arnold L. Rheingold,Vesa Nevalainen.Chiral Camphor-Based 1,3- and 1,4-Amino Alcohols and Aminodiols as Ligands for Diethylzinc Addition to Aldehydes[J].International Journal of Organic Chemistry,2018,8(2):240-263.

1辛浩波,杨玉伟,唐学明.羧酸配体对钼体系合成1,2-聚丁二烯的影响[J].石油化工,1990,19(8):530-535. 被引量：1
2Zhi Guo Qiao Tian Hua Shen Zhen Fang Fu Jun Qi Li Hong Wang Qing Bao Song.The first catalytic asymmetric addition of diethylzinc to aldehyde promoted by chiral thiourea[J].Chinese Chemical Letters,2011,22(11):1265-1268.
3罗梅,黄永华,汪磊,尹浩.Synthesis and Crystal Structure of Cobalt(Ⅱ) and Copper(Ⅱ) Complexes Involving L-Aamino Alcohols[J].Chinese Journal of Structural Chemistry,2014,33(11):1655-1660.
4冯焱,姜标.A C2-Symmetric Amino Alcohol Catalysts Asymmetric Addition of Diethylzinc to Aromatic Aldehydes[J].厦门大学学报（自然科学版）,1999,38(S1):169-169.
5Liang Yin Chao Feng Wang Huan Ling Wang Rong Li Jian Tai Ma.Novel Fréchet-type dendritic BINOL ligands and their applications in Ti(IV) complex catalyzed asymmetric addition of diethylzinc to aldehydes[J].Chinese Chemical Letters,2007,18(12):1487-1489.
6Chong Zhao RAN,Lin XIA,Pei Zhou NI(Division of Medicinal Chemistry, China Pharmaceutical University,Naming 210009).The Influence of Ketones on the Formation of Symmetrical Secondary Amine: A New Method for Preparation of N, N-Bis-(dimethoxyphenylethyl)amine[J].Chinese Chemical Letters,1999,10(11):895-898.
7Qian Yong XU,Hong Fang YANG,Xin Fu PAN,Guang Ming ZHU.The Steric Effect of trans-(1S,2S)-1-Substituted-2-(N,N-dialkyl-amino)-1-indanol Derivatives as Chiral Ligands in the Catalytic Enantioselective Addition of Diethylzinc to Aldehydes[J].Chinese Chemical Letters,2002,13(11):1029-1032.
8张伟强,陈立仁,殷元骐,韩小茜.Chiral tetrahedral complex catalyzing asymmetric addition of diethylzinc to benzaldehyde[J].Science China Chemistry,2002,45(5):481-487. 被引量：1
9HUI,Xin-Ping XU,Peng-Fei GAU,Han-Mou.Enantioselective Addition of Diethylzinc to Aldehydes Catalyzed by N-Sulfonylated Amino Alcohols[J].有机化学,2004,24(z1).
10MIAO Ru,XU ZhenXiang,HUANG ZhiTang,CHEN ChuanFeng.Enantiopure inherently chiral calix[4]arene derivatives containing quinolin-2-yl-methanol moiety:Synthesis and application in the catalytic asymmetric addition of diethylzinc to benzaldehyde[J].Science China Chemistry,2009,52(4):505-512. 被引量：1

Chinese Chemical Letters

2001年第12期

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Asymmetric Addition of Diethylzinc to Aldehydes Catalyzed by Chiral γ_Amino Alcohols 被引量：1

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