摘要
This paper provides a summarized review on the kinetics of vinyl chloride homopolymerization in the absence and presence of chain transfer agents, of VC/DAP(diallyl phthalate) copolymerization with chain extension and/or slightly crosslinking functions, and of vinylidene chloride/VC random copolymerization. Models of rate, degree of polymerization or molecular weight, copolymer composition, gel fraction and crosslinking density were proposed and interpreted mechanistically.
This paper provides a summarized review on the kinetics of vinyl chloride homopolymerization in the absence and presence of chain transfer agents, of VC/DAP(diallyl phthalate) copolymerization with chain extension and/or slightly crosslinking functions, and of vinylidene chloride/VC random copolymerization. Models of rate, degree of polymerization or molecular weight, copolymer composition, gel fraction and crosslinking density were proposed and interpreted mechanistically.
