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陶瓷釉矿物学特征的电子自旋共振(ESR)研究 被引量:2

Study on the Mineralogic Characteristics of Ceramic Glaze by ESR
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摘要 This article introduces the change trend of impurity ions Fe 3+ and Mn 2+ in minerals which compose of glaze at raw and baked at different temperatures. Experiment results show that white glaze has a batch (aix strip) of overfine structure spectrum of Mn 2+ which pile up at the Fe 3+ spectrum at g =2. There is a Fe 3+ spectrum at g =4.3 as the baked temperature is higher while the Fe 3+ wide spectrum at g =2 intensities and Mn 2+ spectrum disappears. When temperature reaches 1300℃, the wide spectrum of Fe 3+ disappears but Fe 3+ spectrum at g = 4.3 intensities. Brown glaze at raw has no Mn 2+ spectrum,just has a wide spectrum at g =2. When the baked temperature is higher, the wide spectrum become narrower and intensities. This article introduces the change trend of impurity ions Fe 3+ and Mn 2+ in minerals which compose of glaze at raw and baked at different temperatures. Experiment results show that white glaze has a batch (aix strip) of overfine structure spectrum of Mn 2+ which pile up at the Fe 3+ spectrum at g =2. There is a Fe 3+ spectrum at g =4.3 as the baked temperature is higher while the Fe 3+ wide spectrum at g =2 intensities and Mn 2+ spectrum disappears. When temperature reaches 1300℃, the wide spectrum of Fe 3+ disappears but Fe 3+ spectrum at g = 4.3 intensities. Brown glaze at raw has no Mn 2+ spectrum,just has a wide spectrum at g =2. When the baked temperature is higher, the wide spectrum become narrower and intensities.
出处 《矿物岩石地球化学通报》 CAS CSCD 1999年第4期295-298,共4页 Bulletin of Mineralogy, Petrology and Geochemistry
基金 贵州省自然科学基金
关键词 陶瓷釉 ESR 杂质离子 ceramic glaze ESR inpurity ion
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参考文献1

  • 1蔡秀成,戴粹新.试论景德镇传统“石灰——碱釉”的油(煤)窑产品发黄的机理[J]中国陶瓷,1987(04).

同被引文献12

  • 1胡海泉.日本陶瓷材料研究现状的概述[J].中国陶瓷,1987,(4):34-38.
  • 2蔡秀成 戴碎新.试论景德镇传统‘石灰-碱釉”的油(煤)窑产品发黄机理[J].中国陶瓷,1987,(4):19-25.
  • 3唐荣炳,矿物岩石地球化学通报,1999年,18卷,4期,295页
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  • 8姚军,赵瑞华,陆小玄,徐如恬.电瓷显微结构分析[R].西安电瓷所,1992.114-115.
  • 9严东生.陶瓷的显微结构与性能,Ⅰ.陶瓷显微结构的形成及其现代研究方法[J].硅酸盐学报,1981,9(1):64-79.
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