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Bimolecular Self-Condensation of Pyrrolizinones Induced byGrignard Reagent

Bimolecular Self-Condensation of Pyrrolizinones Induced by Grignard Reagent
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摘要 The products of pyrrolizinones with 3-methoxyphenyl magnesium bromide were bimolecular condensation compounds, not the related alcohol, and they were confirmed by IR, H-1-NMR, C-13-NMR. HMQC, HMBC. NOE-differ., MS and Elemental Anal.. This indicated that Grignard reagent is a catalyst here. The products of pyrrolizinones with 3-methoxyphenyl magnesium bromide were bimolecular condensation compounds, not the related alcohol, and they were confirmed by IR, H-1-NMR, C-13-NMR. HMQC, HMBC. NOE-differ., MS and Elemental Anal.. This indicated that Grignard reagent is a catalyst here.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 1999年第11期893-894,共2页 中国化学快报(英文版)
关键词 pyrrolizinone SELF-CONDENSATION CHARACTER pyrrolizinone self-condensation character
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