Reductive Cleavage of S-S Bond by Sm/NiCl_2 or Sm/NiCl_2·6H_2O System: A New Method for the Preparation of Thiolesters

Reductive Cleavage of S-S Bond by Sm/NiCl_2 or Sm/NiCl_2·6H_2O System: A New Method for the Preparation of Thiolesters

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摘要 Disulfides were reduced by the Sm/NiCl2 or Sin/NiCI_2 6H_2O system to generate thiolateanion. which reacted further with anhydrides or acyl chlorides to afford thiolesters in good yieldsunder mild and neutral conditions. Disulfides were reduced by the Sm/NiCl2 or Sin/NiCI_2 6H_2O system to generate thiolateanion. which reacted further with anhydrides or acyl chlorides to afford thiolesters in good yieldsunder mild and neutral conditions.

作者 Hua Yue WU Red Er CHEN Yong Min ZHANG(Department of Cheniistry, Wenzhou Normal College, Wenzhou, 325000)(Departnieni of Chemistry. Zhejiang University at Xixi Campus, Hangzhou, 310028)

出处《Chinese Chemical Letters》 SCIE CAS CSCD 1999年第11期899-902,共4页 中国化学快报（英文版）

关键词 Samarium-nickel (II) chloride. disulfide thiolester. Samarium-nickel (II) chloride. disulfide, thiolester.

分类号 O614.813 [理学—无机化学]

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Chinese Chemical Letters

1999年第11期

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Reductive Cleavage of S-S Bond by Sm/NiCl_2 or Sm/NiCl_2·6H_2O System: A New Method for the Preparation of Thiolesters

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