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Propensity Rules in Rotational Inelastic Collisions of NH_2(■A_1) under Molecular Beam Condition

Propensity Rules in Rotational Inelastic Collisions of NH_2 (■A_1) under Molecular Beam Condition
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摘要 In this paper, it is the first time to report the study on the state-to-state rotational energytransfer (RET)of NH2 (A1)(0,9,0)under molecular beam condition in detail. Through asystematic study of the relative population transferred as functions of initially excited quantumstate, including different Ka, nuclear-spin, and even spin-doublet. some propensity rules wereobtained directly. In this paper, it is the first time to report the study on the state-to-state rotational energytransfer (RET)of NH2 (A1)(0,9,0)under molecular beam condition in detail. Through asystematic study of the relative population transferred as functions of initially excited quantumstate, including different Ka, nuclear-spin, and even spin-doublet. some propensity rules wereobtained directly.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 1999年第2期147-150,共4页 中国化学快报(英文版)
关键词 Single collision asymmetry top radical BET propensity rule Single collision, asymmetry top radical, BET, propensity rule
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