A Novel Stereoseletive Approach to (E)-Vinylic Selenides

A Novel Stereoseletive Approach to (E)-Vinylic Selenides

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摘要 The insertion of elemental selenium into the Csp(2)-Zr bond of alkenylchloro-zirconocenes affords (E)-vinylseleno zirconocenes, which were trapped by alkyl halides giving (E)-vinylic selenides in moderate to good yields. The insertion of elemental selenium into the Csp(2)-Zr bond of alkenylchloro-zirconocenes affords (E)-vinylseleno zirconocenes, which were trapped by alkyl halides giving (E)-vinylic selenides in moderate to good yields.

作者 Jun Hua WANG Xian HUANG(Department of Chemistry. Zhejiang University(Campus Xixi). Hangzhou 310028)

出处《Chinese Chemical Letters》 SCIE CAS CSCD 1999年第6期437-440,共4页 中国化学快报（英文版）

关键词 hydrozirconation reaction INSERTION vinylseleno zirconocenes vinylic selenides hydrozirconation reaction insertion vinylseleno zirconocenes vinylic selenides

分类号 O627 [理学—有机化学]

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1陈仁尔,吴华悦,张永敏.A Novel Method for the Synthesis of Selenoesters and Unsymmetrical Aryl Selenides by Sm/cat. CoCl_3 System[J].厦门大学学报（自然科学版）,1999,38(S1):328-328.
2Hua Rong ZHAO,Xin Jian ZHAO,Xian HUANG.A Convenient Synthesis of Diacyl Selenides by Selenium Transfer Reaction of Primary Selenoamides[J].Chinese Chemical Letters,2001,12(10):873-874. 被引量：1
3WU Jianyi,LU Genliang, MA Zhixian,CHEN Jian.Novel Syntheses of Aryl and Benzyl Selenides Promted by Metallic Zinc in Aqueous Media[J].Chemical Research in Chinese Universities,2000,16(2):182-184.
4Zhi Zhen HUANG and Guo Chun LAN(Department of Chemistry, Hangzhou University, Hangzhou, 310028).Synthesis of α-Seleno Substituted Semistabilized Arsonium Ylide and Its Wittig Reaction[J].Chinese Chemical Letters,1998,9(2):117-119.
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Chinese Chemical Letters

1999年第6期

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A Novel Stereoseletive Approach to (E)-Vinylic Selenides

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