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Synthesis of New Cyclic Phosphate of Arylglyoxylonitrile Oximeand Their Diastereomers

Synthesis of New Cyclic Phosphate of Arylglyoxylonitrile Oxime and Their Diastereomers
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摘要 Keeping in view the biological activities of 1,3,2-dioxaphosphorinane-2-one and oxime esters. some compounds possessing these two moieties have been synthesized. The configurational assignment and the ratio of cis/trans diastereomers of target products were performed on basis of H-1 NMR. P-31 NMR and confirmed by X-ray diffraction analysis. Keeping in view the biological activities of 1,3,2-dioxaphosphorinane-2-one and oxime esters. some compounds possessing these two moieties have been synthesized. The configurational assignment and the ratio of cis/trans diastereomers of target products were performed on basis of H-1 NMR. P-31 NMR and confirmed by X-ray diffraction analysis.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 1999年第6期445-446,共2页 中国化学快报(英文版)
关键词 1 3 2-dioxaphosphorinane-2-one arylglyoxylonitrile DIASTEREOMERS 1,3,2-dioxaphosphorinane-2-one arylglyoxylonitrile diastereomers
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