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Dual-parameter Correlation Analysis of the Fluorescence Data of 1-Methyl-2-formyl-5-substituted Pyrrole(4-nitrophenyl)hydrazones

Dual-parameter Correlation Analysis of the Fluorescence Data of 1-Methyl-2-formyl-5-substituted Pyrrole(4-nitrophenyl)hydrazones
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摘要 By using 1-methyl-2-formyl-5 -Y-substituted pyrrole (4-nitrophenyl)hydrazones as a model for nitrogen-containing heterocyclic aromatic compounds, the emission wavelength [lambda(max(em))] values df their fluorescence spectra have been measured. Correlation results show that the Delta E-em values are mainly affected by polar effects, but spin-delocalizatin effects also exist. By using 1-methyl-2-formyl-5 -Y-substituted pyrrole (4-nitrophenyl)hydrazones as a model for nitrogen-containing heterocyclic aromatic compounds, the emission wavelength [lambda(max(em))] values df their fluorescence spectra have been measured. Correlation results show that the Delta E-em values are mainly affected by polar effects, but spin-delocalizatin effects also exist.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 1999年第6期499-502,共4页 中国化学快报(英文版)
关键词 fluorescence spectra correlation analysis dual-parameter equation spin-delocalization effect polar effect 1-methyl-2-formyl-5-Y-substituted pyrrole (4-nitrophenyl)hydrazones fluorescence spectra correlation analysis dual-parameter equation spin-delocalization effect polar effect 1-methyl-2-formyl-5-Y-substituted pyrrole (4-nitrophenyl)hydrazones
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