摘要
把杂化轨道理论与价层电子对互斥理论综合考虑,可以成功地判断和解释共价型分子或离子的空间构型,该法不但克服了杂化轨道理论无法判断中心原子杂化类型的不足,也弥补了价层电子对互斥理论不能说明成键原理的缺陷。
Comprehensive consideration of Hybrid Orbital Theory and Valence Shell Electron Pair Repulsion Theory can successfully judge and explain spatial configuration of covalent molecules and ions. The method can not only conquers insufficient of Hybrid Orbital Theory in hybrid types of center atom not being able to be judged,and but remedy a defect of Valence Shell Electron Pair Repulsion Theory in bonding process of covalent molecules and ions not being able to be explained.
出处
《北京石油化工学院学报》
1998年第1期43-49,共7页
Journal of Beijing Institute of Petrochemical Technology
关键词
分子的空间构型
杂化轨道理论
价层电子对互斥理论
spatial configuration of molecules
hybrid orbital theory
valence shell elec- tron pair repulsion theory