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Model Calculation of ln γ_i^0 for Solute Elements in Copper-base Alloy Systems

Model Calculation of ln γ i 0 for Solute Elements in Copper base Alloy Systems
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摘要 A calculation formula of ln γ i 0 for solute element i in liquid alloys was derived by use of free volume theory and Miedema formation enthalpy model. The values of ln γ i 0 of solute elements in liquid copper at 1273 K were obtained. The results obtained show that the coincidence rate of sign (positive or negative) was 90% for the calculated and experimental values, which were basically in the same magnitude. A calculation formula of ln γ i 0 for solute element i in liquid alloys was derived by use of free volume theory and Miedema formation enthalpy model. The values of ln γ i 0 of solute elements in liquid copper at 1273 K were obtained. The results obtained show that the coincidence rate of sign (positive or negative) was 90% for the calculated and experimental values, which were basically in the same magnitude.
出处 《Rare Metals》 SCIE EI CAS CSCD 1998年第4期48-53,共6页 稀有金属(英文版)
关键词 Free volume theory Miedema formation model Activity coefficient γ i 0 Copper base alloy system Free volume theory, Miedema formation model, Activity coefficient γ i 0, Copper base alloy system
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