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Conformational statistics of polymer chain terminally attached to wall(Ⅱ)——SAW model tail chain

Conformational statistics of polymer chain terminally attached to wall(Ⅱ)——SAW model tail chain
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摘要 The SAW tail chains were studied.The permitted conformational number and the mean square end-to-end distance as a function of the chain length N for such a model tail chain were obtained by computer simulations,including the exact enumeration and Monte Carlo method.These two basic quantities obeyed the relations deduced from the scaling law.The critical exponents and the lattice indexes were given by fitting the data of the computer experiments.It has been shown that there is a certain extension in the size of the SAW tail chains as well as the NRW tail chains in the direction normal to the wall.The normal component of the mean square end-to-end distance is almost twice as large as the parallel component of the short chain SAW.However,as N→∞,the effect of the wall on the chain conformation becomes a little weak because of the self-avoiding behavior for the model.That is quite different from the case of the NRW tail chain. The SAW tail chains were studied.The permitted conformational number and the mean square end-to-end distance as a function of the chain length N for such a model tail chain were obtained by computer simulations,including the exact enumeration and Monte Carlo method.These two basic quantities obeyed the relations deduced from the scaling law.The critical exponents and the lattice indexes were given by fitting the data of the computer experiments.It has been shown that there is a certain extension in the size of the SAW tail chains as well as the NRW tail chains in the direction normal to the wall.The normal component of the mean square end-to-end distance is almost twice as large as the parallel component of the short chain SAW.However,as N→∞,the effect of the wall on the chain conformation becomes a little weak because of the self-avoiding behavior for the model.That is quite different from the case of the NRW tail chain.
机构地区 Textile College
出处 《Science China Chemistry》 SCIE EI CAS 1997年第1期1-8,共8页 中国科学(化学英文版)
基金 supported by the National Natural Science Foundation of China
关键词 polymer conformational STATISTICS TAIL chain self-avoiding WALK MUSHROOM CONFORMATION polymer,conformational statistics,tail chain,self-avoiding walk,mushroom conformation
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参考文献12

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