摘要
The structural rearrangement of quenched titanate glasses reheated at T-g was investigated by ESR and IR spectroscopies. Front the ESR observations it is suggested that the structure was readjusted and became more compact after the heat-treatment. A removal of residual vacancies is related to the diffusion of oxygen ions. The combination of more oxygen with titanium ions to form titanium-oxygen polyhedra and the transformation of boron-oxygen groups are confirmed front IR spectra. Some physical properties are improved after heating.
The structural rearrangement of quenched titanate glasses reheated at T-g was investigated by ESR and IR spectroscopies. Front the ESR observations it is suggested that the structure was readjusted and became more compact after the heat-treatment. A removal of residual vacancies is related to the diffusion of oxygen ions. The combination of more oxygen with titanium ions to form titanium-oxygen polyhedra and the transformation of boron-oxygen groups are confirmed front IR spectra. Some physical properties are improved after heating.
