炔烃立体选择性还原制备Z—或E—烯烃的近期方法

Recent Methods for the Stereoselective Reduction of Alkynes to Z-or E-Alkenes

在有机化合物,尤其是天然产物中,碳碳双键的构型往往对其生理活性起了决定性的作用。本文综述了在有机合成领域中,通过炔烃立体选择性还原制备Z—或E—烯烃的近期方法。

The configuration of double bonds in organic compounds, espcialy in aliphatic natural products, often determind their biological activities. The article reviews recent methods used in organic synthsis field for the stereoselective reduction of alkynes to Z—or E—alkene.