摘要
Silica the N, N'-bis[-2-(benzimidazolylmethyl)]amino-ferrous acetate complexes (Ⅳ)catalyzed monooxygenation of cyclohexane to cyclohexanol with the turnover muber(equrvalent C%= 11. 2)under mild conditions.The methylene bule is the most effective electron transfer agent which can also regulate products distribution. The iron content of the polymer-supported complexes, the redox potentials and the concentration of methylene blue greatly affect the activity and selectivity of the complex (Ⅳ).
Silica the N, N'-bis[-2-(benzimidazolylmethyl)]amino-ferrous acetate complexes (Ⅳ)catalyzed monooxygenation of cyclohexane to cyclohexanol with the turnover muber(equrvalent C%= 11. 2)under mild conditions.The methylene bule is the most effective electron transfer agent which can also regulate products distribution. The iron content of the polymer-supported complexes, the redox potentials and the concentration of methylene blue greatly affect the activity and selectivity of the complex (Ⅳ).
