摘要
The association constants (K.), free energy (△G￣0), enthalpy (△H￣0) and entropy (△S0) changes were determined for the inclusion complexation of β-cyclodextrin with a series of 1-substituted naphthslenes in aqueous solution. The △H0-T△S0 plot for the β-cyclodextrin complexes with naphthalene derivatives show a linear relationship with slope of 0. 98and intercept of 14. 67. The results were discussed in terms of enthalpy-entropy compensation.
The association constants (K.), free energy (△G￣0), enthalpy (△H￣0) and entropy (△S0) changes were determined for the inclusion complexation of β-cyclodextrin with a series of 1-substituted naphthslenes in aqueous solution. The △H0-T△S0 plot for the β-cyclodextrin complexes with naphthalene derivatives show a linear relationship with slope of 0. 98and intercept of 14. 67. The results were discussed in terms of enthalpy-entropy compensation.
