摘要
cis-[Pd(met)(D2O)2]2+ promoted hydrolysis of AcMet-Gly was monitored by H NMR spectroscopy. The observed rate constants, Kobs, strongly depend on the mole ratio of cis-[Pd(met)(D2O)2]2+ to AcMet-Gly.At least,one aqua ligand for each Pd(II)is necessary for fast hydrolysis reaction observed. Two aqua ligands of each Pd(II) make the reaction faster.
cis-[Pd(met)(D2O)2]2+ promoted hydrolysis of AcMet-Gly was monitored by H NMR spectroscopy. The observed rate constants, Kobs, strongly depend on the mole ratio of cis-[Pd(met)(D2O)2]2+ to AcMet-Gly.At least,one aqua ligand for each Pd(II)is necessary for fast hydrolysis reaction observed. Two aqua ligands of each Pd(II) make the reaction faster.
