关于热力学自发过程的研究

STUDY ON THE CONCEPTION OF THERMODYNAMIC SPONTENEOUS PROCESSES

应用逻辑推理和概念比较法研究问题,给热力学自发过程一个严格定义,使许多混淆得以澄清,对经典著作中的外部和内部不可逆过程作了新的解释。

Thermodynamic sponteneous processes is an important comception in physical chemistry and chemical thermodynamics. But to be regret,it has not a clear and rigorous definition till then,This makes much debates and disputes in the teaching circle and much diffi-cults in teaching. Using a method of logic reasoning and contrats of comeptions,the author makes a deep study on it,discloses some contraditions in it,clears up some confuses about it,and by the way,gives a new interpretation to the'internal and external irreversible processes'in the classic works,makes the conception revival and much useful in thermodynamic analysis