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Homologation of Taxol Side Chain via Arndt-Eistert Reaction Involving the Wolff Rearrangement 被引量:1

Homologation of Taxol Side Chain via Arndt-Eistert Reaction Involving the Wolff Rearrangement
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摘要 Homologation of protected taxol side chen 8 from 4 was accomplished stereospecifically through the key intermediate diazo ketone 5 which was actually isolated. The structures of 5 and 7 were identified by spectrometric methods, mainly 1H-NMR, 1R, 13C-NMR and DEPT techniques. Homologation of protected taxol side chen 8 from 4 was accomplished stereospecifically through the key intermediate diazo ketone 5 which was actually isolated. The structures of 5 and 7 were identified by spectrometric methods, mainly 1H-NMR, 1R, 13C-NMR and DEPT techniques.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 1996年第12期1077-1078,共2页 中国化学快报(英文版)
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