摘要
s:Protodesilylation of(2H)-pyridazinon-5-yl silylmethyl sulfides 1 proceeds smoothly withcleavage of sp3 hybridized carbon-silicon bond in the presence of catalytic amount of sodiumhydroxide at room temperature. The presence of aryl R on silicon atom and (2H)-pyridazinon-5-ylgroup on sulfur atom plays a critical role in the occurrence of this reaction.
s:Protodesilylation of(2H)-pyridazinon-5-yl silylmethyl sulfides 1 proceeds smoothly withcleavage of sp3 hybridized carbon-silicon bond in the presence of catalytic amount of sodiumhydroxide at room temperature. The presence of aryl R on silicon atom and (2H)-pyridazinon-5-ylgroup on sulfur atom plays a critical role in the occurrence of this reaction.
