SYNTHESIS　AND　MAGNETISM　OF　μ－OXAMIDO　COPPER（Ⅱ）－LANTHANIDE（Ⅲ）HETEROBINUCLEAR　COMPLEXES

SYNTHESIS AND MAGNETISM OF μ-OXAMIDO COPPER(Ⅱ)- LANTHANIDE(Ⅲ)HETEROBINUCLEAR COMPLEXES

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摘要 Four new μ-oxamido heterobinuclear complexes of CuII-LnIII (Ln: Y,Pr, Ho. Gd)were synthesized and characterized. The magnetic susceptibility measurements(4～300K)of the CuII-GdIII complex indicate a weak ferromagnetic interaction between thetwo metal ions, with the exchange integral JCu-Gd=2.03 cm-1. Four new μ-oxamido heterobinuclear complexes of CuII-LnIII (Ln: Y,Pr, Ho. Gd)were synthesized and characterized. The magnetic susceptibility measurements(4～300K)of the CuII-GdIII complex indicate a weak ferromagnetic interaction between thetwo metal ions, with the exchange integral JCu-Gd=2.03 cm-1.

作者 Cui Wei YAN(Department of Biology, Qufu Normal University,Qufu Shandong, 273165)Yan Tuan LI(Department of Chemistry, Qufu Normal University,Qufu Shandong.273165)Dai Zheng LIAO(Department of Chemistry, Nankai University. Tianjin, 300071)

出处《Chinese Chemical Letters》 SCIE CAS CSCD 1996年第7期681-684,共4页 中国化学快报（英文版）

分类号 O627 [理学—有机化学]

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Chinese Chemical Letters

1996年第7期

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