摘要
The magnetic susceptibility of (Bu4N)(NI(MEDT)2) and (Bu4N)(Ni(PHDT)2)(MEDT:5-methyl-6-hydro-1, 4-dithiin-2, 3-dithiolate, PHDT: 5-phenyl-6-hydro-1.4-dithiin- 2,3-dithiolate) was measured in the temperature range of 75-300K. The magnitudeof magnctic moments is consistent,with a doublet state arising from Ni(Ⅲ).Antiferromagnetic properties were discussed in consideration of molecularstructure.
The magnetic susceptibility of (Bu4N)(NI(MEDT)2) and (Bu4N)(Ni(PHDT)2)(MEDT:5-methyl-6-hydro-1, 4-dithiin-2, 3-dithiolate, PHDT: 5-phenyl-6-hydro-1.4-dithiin- 2,3-dithiolate) was measured in the temperature range of 75-300K. The magnitudeof magnctic moments is consistent,with a doublet state arising from Ni(Ⅲ).Antiferromagnetic properties were discussed in consideration of molecularstructure.
